China 6,6',6''-((1,3,5-Triazine-2,4,6-triyl) tris (azanediyl)) trihexanoic acid Supplier & Products

Industry-Leading Technical Grade Corrosion Inhibitors (CAS 80584-91-4 / TC-50) | High-Gain Information & Technical Whitepaper by JIMPOCHEM

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Technical Whitepaper: 6,6',6''-((1,3,5-Triazine-2,4,6-triyl) tris (azanediyl)) trihexanoic acid

Comprehensive Chemical Structure, Mechanism of Action, and Performance Metrics

6,6',6''-((1,3,5-Triazine-2,4,6-triyl) tris (azanediyl)) trihexanoic acid (CAS No: 80584-91-4), commercially widely referred to as 2,4,6-Tri-(6-aminocaproic acid)-1,3,5-triazine or TC-50 corrosion inhibitor, represents a landmark advancement in eco-friendly metalworking fluid chemistry and aqueous anti-corrosion science. Engineered with a symmetrical triazine core substituted with three carboxylic acid tail groups, this macromolecular compound delivers superior passivating protection across ferrous and multi-metal substrates under intense hydrodynamic stress.

Key Chemical Insight: Unlike legacy nitrites or secondary amine-based inhibitors, TC-50 prevents nitrosamine formation entirely, aligning with stringent global environmental standards such as REACH, EU RoHS, and US EPA regulations while operating at low treat rates (0.15%–0.8%).

1. Molecular Architecture & Physicochemical Identity

The molecular configuration features a rigid 1,3,5-triazine ring offering exceptional thermal and hydrolytic stability. The three peripheral carboxyl-terminated hexanoic acid arms impart powerful water solubility when neutralized with alkanolamines (such as Triethanolamine or Monoethanolamine), while creating a multi-dentate chelation site for surface iron ($\text{Fe}^{2+}/\text{Fe}^{3+}$) ions.

Property Parameter Technical Specification Standard Testing Protocol
Chemical Name 6,6',6''-((1,3,5-Triazine-2,4,6-triyl) tris (azanediyl)) trihexanoic acid IUPAC Standard Nomenclature
CAS Registry Number 80584-91-4 CAS Index Database
Molecular Formula / Weight $\text{C}_{21}\text{H}_{36}\text{N}_{6}\text{O}_{6}$ / 468.55 g/mol Mass Spectrometry (MS)
Appearance (25°C) White to off-white crystalline powder Visual Inspection
Active Content $\ge 98.5\%$ HPLC / Titration Analysis
Melting Point Range 194°C – 198°C Differential Scanning Calorimetry (DSC)
Water Solubility (Neutralized) Completely Soluble in water at pH > 7.5 Gravimetric Analysis
Ash Content $\le 0.5\%$ Muffle Furnace Calcination

2. Passivation & Surface Chemistry Mechanism

When dissolved in aqueous media with alkanolamines, 6,6',6''-((1,3,5-Triazine-2,4,6-triyl) tris (azanediyl)) trihexanoic acid forms anionic carboxylate species. These carboxylate groups adsorb rapidly onto anodic sites of metal surfaces, forming an insoluble, hydrophobic chemisorbed monomolecular barrier film. This passive monolayer blocks electron transfer during electrochemical oxidation, drastically suppressing ferric hydroxide ($Fe(OH)_3$) and rust formation even under hard water conditions ($>20^\circ\text{dH}$).

Global Procurement Trends & Industry Drivers

Transforming Industrial Corrosion Control in the Green Chemistry Era

Phase-out of Nitrosamines & DEA

Global environmental regulatory bodies (ECHA, EPA) are restricting secondary amines and sodium nitrites. TC-50 offers a non-hazardous, zero-nitrosamine alternative with zero cobalt leaching, securing long-term compliance for metalworking fluid formulators.

Electric Vehicle (EV) Machining Shift

EV lightweight structural components require complex machining of aluminum-steel hybrid assemblies. Triazine trihexanoic acid formulations ensure zero galvanic stain, non-foaming lubrication, and multi-metal safety across high-speed CNC processes.

Supply Chain Consolidation in China

Global chemical purchasers are migrating toward integrated Chinese manufacturers like JIMPOCHEM for long-term price stability, guaranteed spot supply, high batch consistency, and REACH-ready technical dossiers.

Macro-Industry Application Solutions

Tailored Formulations for Automotive, Water Treatment, and Heavy Machinery

Synthetic Metalworking Fluids (MWF)

Provides exceptional cast iron corrosion protection (Herbert Test 0/0 grade) at low dosage without generating foam in soft water systems. Compatible with synthetic esters, polyalkylene glycols (PAG), and biocides.

Industrial Water Treatment

Acts as an effective non-organophosphonate scale and corrosion inhibitor in closed-loop cooling water circuits. Stable at elevated temperatures ($>120^\circ\text{C}$) and resistant to oxidative degradation by chlorine/bromine biocides.

Water-Borne Coatings & Cleaners

Serves as an in-can corrosion inhibitor and flash-rust preventative for aqueous industrial alkaline cleaners (pH 8.5–11), protecting processed steel parts during inter-operational storage.

About JIMPOCHEM CO., LTD

Designated Chemical Service Provider & High-End Chemical Raw Material Manufacturer

JIMPOCHEM CO., LTD was established in 2010 and is headquartered in the Chemical Industry Park of Jinan City, Shandong Province. The company covers an area of over 500 acres and is a professional chemical raw material manufacturer that integrates research and development, production, sales, and technical services. Its core focus is on high-end fine chemicals and cosmetic raw materials. We have obtained multiple product-related certifications, including ISO quality system certification and environmental management system certification, and are committed to providing high-quality chemical products and one-stop procurement service solutions to global customers.

Our core team comprises experts with over 10 years of experience in the chemical industry. This enables us not only to provide professional products but also to offer solutions in product development, formula optimization, and supply chain management, meeting the personalized needs of diverse clients. We provide high-quality products and services, and our products are exported to over 200 countries and regions in Europe, America, Southeast Asia, the Middle East, and Oceania, serving more than 5,000 international companies. We have also established long-term strategic partnerships with many internationally renowned chemical companies, becoming a trusted "designated chemical service provider" for numerous clients.

16+
Years Industry Experience
500+
Acres Modern Facility
200+
Countries Exported
5000+
Global Enterprise Clients

Core Competitive Advantages

Supply Chain & Production Capacity

Leveraging years of industry experience, we have established stable raw material procurement channels and partnered with top global chemical raw material suppliers, ensuring stable raw material quality and ample supply. Our modern production base employs an intelligent control system to automate and digitally manage the production process, balancing large-scale production with flexible customization needs.

Rigorous Quality Control System

Adhering to the philosophy that "quality is the lifeline of an enterprise," the company has established a comprehensive quality control system. From raw material warehousing and inspection, real-time monitoring of production process, to full-item inspection of finished products before shipment, every step adheres to strict technical specifications with batch traceability.

Green & Sustainable Commitment

In response to the global "dual-carbon" strategy, the company focuses on the research and development and production of green chemical products, adopting environmentally friendly production processes and optimizing wastewater, waste gas, and waste residue treatment systems to achieve compliant emissions and sustainable growth.

Technical Roadmap & Future Innovations (2025–2030)

Advancing Next-Generation Water-Soluble Corrosion Inhibition Technologies

1. Bio-Sourced Caproate Precursor Integration

JIMPOCHEM R&D center is actively pioneering bio-based 6-aminocaproic acid synthesis derived from renewable agricultural feedstocks. This initiative aims to reduce the product's net carbon footprint by over 40% while preserving identical electrochemical performance.

2. Synergistic Multi-Metal Passivation Complexes

Developing pre-neutralized multi-functional additive blends combining 6,6',6''-((1,3,5-Triazine-2,4,6-triyl) tris (azanediyl)) trihexanoic acid with copper passivators (such as BTA/TTA) and zirconium salts for ultra-thin nanostructured protective oxide layers.

Localization Support & Global Regulatory Assurance

De-Risking Overseas Procurement for Global Buyers

Navigating chemical import compliance requires airtight documentation and localized logistical precision. JIMPOCHEM provides international partners with comprehensive regulatory backing to streamline customs clearance and factory audits:

REACH Certified

Full EU REACH tonnage coverage for unrestricted imports across Europe.

GHS & SDS

Multi-lingual Safety Data Sheets updated to GHS Rev. 10 standards.

ISO 9001 / 14001

Internationally audited quality management and environmental systems.

Flexible Packaging

Custom 25kg bags, 500kg super-sacks, and OEM private labeling solutions.

Factory Tour & Facility Infrastructure

500+ Acres Industrial Site | Advanced Analytical & Automated Production Systems

Frequently Asked Questions (FAQ)

Technical Clarifications for Procurement Directors & Chemical Engineers

What is the recommended treat rate for TC-50 (CAS 80584-91-4) in semi-synthetic fluids?
In semi-synthetic metalworking fluid concentrates, the standard dosage ranges from 0.25% to 0.60% by weight. When diluted in water for working solution (e.g., 5% dilution), it maintains superior corrosion control on cast iron (DIN 51360/2 chip test 0/0).
How should 6,6',6''-((1,3,5-Triazine-2,4,6-triyl) tris (azanediyl)) trihexanoic acid be neutralized?
The crystalline powder is insoluble in pure water. It requires stoichiometric neutralization with alkanolamines such as Triethanolamine (TEA), Monoethanolamine (MEA), or Diglycolamine (DGA) at a pH range of 8.0–9.5 to form water-soluble carboxylate salts.
Does this product suffer from hard water instability or heavy foaming?
No. TC-50 triazine carboxylate salts exhibit outstanding calcium/magnesium hard water tolerance up to 2000 ppm ($112^\circ\text{dH}$) without precipitation or loss of corrosion inhibition, while producing virtually zero foam in high-pressure CNC coolant jets.
What is the typical lead time and shelf life for export orders from China?
JIMPOCHEM maintains spot stock for standard 25kg bags. Export shipments depart Qingdao/Tianjin ports within 7–10 days of order confirmation. The product has a shelf life of 24 months when stored in original sealed packaging under cool, dry conditions.
Is TC-50 compatible with aluminium and non-ferrous metals?
While TC-50 is primarily designed as a powerful ferrous metal passivator, its non-staining nature makes it safe for sensitive aluminum alloys (e.g., 6061, 7075) when combined with standard silicates or phosphonate coupling agents.
Can JIMPOCHEM provide customized formulations or pre-neutralized liquid concentrates?
Yes, our R&D center provides customized synthesis, tailored grain-size milling, and pre-dispersed aqueous amine concentrates to fit your manufacturing process. Contact our technical team for custom OEM requests.

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